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Q.

Consider the hypothetical reaction occuring at T = 298 K

Cl2(g)+2Br(aq)2Cl(aq)+Br2(aq.)

The emf of the cell, when [Cl]=[Br2]=[Br]=0.01M and Cl2 gas is at 1 atm pressure, will be: 

(Eo for the above reaction is = 0.29 volt) 

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a

-0.29 volt

b

0.35 volt

c

0.24 volt

d

0.54 volt

answer is B.

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Detailed Solution

Ecell=0.290.0592log0.01×(0.01)2(0.01)2×1

or Ecell=0.35 volt

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