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Q.

Consider the ionic reaction : HC2O4+PO43HPO42+C2O42. Identify the incorrect statement(s)

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a

HC2O4 and C2O42 are conjugate acid-base pairs

b

The P – O bond order in PO43 is 1.75

c

The C – O bond order in C2O42 is 1.50

d

The above equilibrium mixture can act as a buffer (both acids have nearly the same dissociation constant)

answer is C.

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Detailed Solution

Buffer : Solution of weak acid and its salt.
Since both HC2O5and HPO42 same
dissociation constant the solution can act as buffer.

Question Image

2-resonating structure for each carboxlate ion

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Consider the ionic reaction : HC2O4−+PO4−3⇌HPO42−+C2O42−. Identify the incorrect statement(s)