Q.

 Consider the ionization of H2SO4 as follow:

H2SO4+2H2O2H3O+SO42

The total number of ions furnished by 100 mL of 0.1 M H2SO4 will be

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a

1.8×1023

b

0.12×1023

c

1.2×1023

d

0.18×1023

answer is C.

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Detailed Solution

Given reaction is balanced and according to the balanced chemical reaction, one mole of H2SO4 gives three moles of ions, two moles of H3O and one mole of SO42-.

Number of moles present in 100 mL of 0.1 M of H2SO4 is calculated as:

Molarity=Number of moles of soluteVolume (in L)0.1 M=Number of moles of solute100 mL×1 L1000 mLNumber of moles of solute=0.01 mol

1 mole of H2SO4gives2 mol of H3O0.01 mol of H2SO4=0.01 mol of H2SO4×2 =0.02 mol of H3O

1 mol H2SO4gives1 mol SO42-0.01 mol H2SO4=0.01 mol H2SO4 =0.01 mol SO42-

Therefore, the total number of ions produced by 0.01 moles of H2SO4 is:

Total number of ions produced=Number of H3O+Number of SO42- =0.02 mol+0.01 mol =0.03 mol

Number of ions present in one mole is 6.023×1023. Number of ions present in 0.03 mol is calculated as:

1 mol=6.023×1023 ions0.03 mol=0.03 mol×6.023×1023 ions1 mol =0.18×1023 ions

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