Q.

Consider the ions: S2O32 (X) and S2O42 (Y). How many statements are correct regarding (X) and (Y). (d stands for bond length)

(a) dSS:X<Y

(b) dSO:X<Y

(c) Average oxidation state of S in (X) is less than that in (Y)

(d) In both (X) and (Y), the central S atom is sp3 hybridised   

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Detailed Solution

The ions: S2O32 (X) and S2O42 (Y) can be represented as,

Question Image

 

 

 

 

Average oxidation state of S in (X) is less than that in (Y)

 Avg O.S. =+2  Avg O.S. =+3

The bond length of both S-S and S-O is less in X compared to Y.

    B.L. (SS)        Y>X

 B.L. (SO)Y(151pm)>X(147pm)

Due to l.p. on ''S in 'Y',% in SO bond  and B.L. 

The central S atom is sp3 hybridised in both the molecule.  

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Consider the ions: S2O32− (X) and S2O42− (Y). How many statements are correct regarding (X) and (Y). (d stands for bond length)(a) dS−S:X<Y(b) dS−O:X<Y(c) Average oxidation state of S in (X) is less than that in (Y)(d) In both (X) and (Y), the central S atom is sp3 hybridised