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Q.

Consider the proposed mechanism for the destruction of ozone in the stratosphere:

O3+ClClO+O2ClO+O3Cl+2O2

Which of the statements about this mechanism is correct?

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a

The number of moles of O2 produced equals the number of moles of O3 consumed.

b

Equal amounts of Cl· and ClO· are present.

c

O2 is an intermediate.

d

Cl· is a catalyst.

answer is A.

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Detailed Solution

Overall Reaction

step 1: Cl+O3ClO + O2

 step 2: ClO+ O3  u + O2

Cl (g)+ClO (g) +2O3(g)Cl (g) +ClO (g)+2O3(g) 

2O3(g) 3O2

Cl (g)reactant at step 1, but it is in regenerated in step 2, using generated to step 2Clcatalyst

ClO genenared in step 1  consumes in step 2

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