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Q.

Consider the reaction, 

2A + B → Products 

When concentration of B alone was doubled, the half-life did not change. When the concentration of A alone was doubled, the rate increased by two times. The unit of rate constant for this reaction is

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a

molL-1 s-1

b

s-1

c

Lmol-1 s-1

d

no unit

answer is A.

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Detailed Solution

2A+B→Product

When conc. of B is doubled, the half life did not change, hence reaction is of first order w.r.t. B. When concentration of A is doubled, reaction rate is doubled, hence reaction is of first order w.r.t. A. 

Hence over all order of reaction is 1 + 1 = 2

So, unit of rate constant mol-1 lit s -1

Hence, (1) is correct

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