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Q.

Consider the reaction given below.

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The correct statement(s) applicable to the above reaction is/are

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a

Cl is substituted predominantly

b

Cl is a better leaving group

c

addition of some NaI catalyse the substitution reaction

d

substitution of l in the above reaction required greater activation energy than for Cl

answer is A, C, D.

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Detailed Solution

Steric hindrance plays the most important role in SN2 reaction. Hence, although Cl is poorer leaving group than I, Cl is substituted predominantly in the above reaction due to less steric hindrance at α- carbon, Addition of NaI replace Cl by I and substitution becomes easier

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