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Q.

Consider the reaction, 2A + B products. When concentration of B alone was doubled, the  half– life did not change. When the concentration of A alone was doubled. The rate increased by two times. The unit of rate constant for this reaction is

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a

S-1

b

no unit

c

mol L-1S-1

d

L mol-1S-1

answer is B.

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Detailed Solution

Since doubling the concentration of B does not change half life, the reaction is of 1st or5der w.r.t. B. order of reaction with respect to A = 1 because rate of reaction doubles when concentration of A is doubled keeping concentration of B constant.

 Order of reaction = 1 + 1 = 2 and units of second order reaction are Lmol1sec1

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Consider the reaction, 2A + B →products. When concentration of B alone was doubled, the  half– life did not change. When the concentration of A alone was doubled. The rate increased by two times. The unit of rate constant for this reaction is