Q.

Consider the reaction,

CH3CH2CH2Br+NaCNCH3CH2CH2CN+NaBr

This reaction will be the fastest in

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a

N,N' -dimethylformamide (DMF)

b

ethanol water.

c

methanol

d

 water

answer is C.

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Detailed Solution

The reaction,

CH3CH2CH2Br+NaCNCH3CH2CH2CN+NaBr

 follows SN2 mechanism which is favoured by polar 

 aprotic solvent i.e., N,N'- dimethylformamide (DMF). 

 

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moreover no rearrangement is observed, it is SN2 mechanism

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Consider the reaction,CH3CH2CH2Br+NaCN→CH3CH2CH2CN+NaBrThis reaction will be the fastest in