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Q.

Consider the reversible reaction HCNaqHaq++CNaq- }. At equilibrium, the addition of CNaq-would

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a

reduce HCNaq concentration

b

decrease equilibrium constant

c

 decrease H+ ion concentration

d

increase equilibrium constant

answer is B.

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Detailed Solution

The equilibrium reaction is

HCNaqHaq++CNaq-

When cyanide is added to the reaction mixture, the concentration of cyanide ions increases. The equilibrium will shift in the backward direction so that more cyanide ions will combine with hydrogen ions to nullify the effect of increased cyanide ion concentration. This will also decrease the hydrogen ion concentration, as dissociation of HCN is suppressed.

So, the correct option is (B).

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