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Q.

Consider the two gaseous equilibria,
    A22A          ABA+B
Assume that the ΔrG0   and therefore equilibrium constant are same for both. An enclosure is initially packed with A and B in atomic state. B never dimerises. Which of the following is/are must be correct?
 

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a

Partial pressure of AB is less than partial pressure of  A2

b

Extent of formation of AB is more than that of  A2

c

Number of moles of AB is same as number moles of  A2

d

Mole fraction of AB at equilibrium is dependent on initial partial pressures of  A and B.
 

answer is D.

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Detailed Solution

If an enclosure at high temperature contains equal number of atoms A and B, then, when the temperatures is lowered, and molecules A2 , AB,  B2  form, they do not form in equal numbers, but in the ratio 1:2:1.

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