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Q.

Consider the Vander waals constants a and b for the gases

GasesArNeKrXe 
a (  atm dm6mole-2  )1.30.25.1

4.1

b( 10-2dm3mole-1)3.21.71.0

5.0

Which gas expected to have the highest critical temperature 

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a

Kr

b

Ne    

c

Xe

d

Au

answer is A.

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Detailed Solution

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Tc = 8a 27Rb 

Gas with higher 'a' value lower 'b' value easily liquefied for easily liquefied gas TC is more

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