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Q.

Consider the ΔGf and ΔHf (kJ/mol) for the following oxides. Which oxide can be most easily decomposed to form the metal and oxygen gas?

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a

HgO    ΔG=58.5,    ΔH=90.8

b

PbO    ΔG=187.9,    ΔH=217.3

c

Cu2O    ΔG=146.0,    ΔH=168.8

d

ZnO    ΔG=318.4,    ΔH=348.3

answer is C.

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Detailed Solution

HgOHg+12O2

ΔG=+58.5ΔH=+90.8

Hence, HgO decomposes more easily at a lower temperature than other oxides.

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