Q.

Consider this reaction,

2H2(g)+2NO(g)N2(g)+2H2O(g)

The rate law for this reaction is rate =kH2[NO]2

Under what conditions could these steps represent the mechanism?

 Step 1 : 2NO N2O2

 Step 2: N2O2+H2N2O+H2O

 Step 3: N2O+H2N2+H2O

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a

These steps could be the mechanism if step 3 is the slow step. 

b

These steps cannot be the mechanism under any circumstances.

c

These steps could be the mechanism if step 1 is the slow step.

d

These steps could be the mechanism if step 2 is the slow step.

answer is C.

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Detailed Solution

The response is as follows:

2H2(g)+2NO(g)N2(g)+2H2O(g)

The rate law is as follows:

 Rate =KH2[NO]2

The slowest stage determines the rate of the chemical reaction. Therefore, since the rate of the reaction is dictated by that, we should have 2 molecules of NO and 1 molecule of H2 in the slowest step.

 So, I. 2NO(g)+H2(g)N2(g)+H2O2 (slow) 

 II. H2O2+H2(g)2H2O(g) (fast) 

This might be the reaction's mechanism, according to rate law.

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Consider this reaction,2H2(g)+2NO(g)⟶N2(g)+2H2O(g)The rate law for this reaction is rate =kH2[NO]2Under what conditions could these steps represent the mechanism? Step 1 : 2NO ⇌N2O2 Step 2: N2O2+H2⟶N2O+H2O Step 3: N2O+H2⟶N2+H2O