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Q.

Consider two reactions at 27°C
 (IAB (I order kinetics  (IIXY (Zero order kinetics
If both A and X each having initial concentration 0.1 M and and same initial half life period.
Then find simplest ratio of rate constants for I and II, reactions (KI / KII), (ln2 = 0.7)

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answer is 14.

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Detailed Solution

KI=ln2t1/2=0.7t1/2,KII=0.12×t1/2,KIKII=14

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