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Q.

Considering H2O as a weak field ligand, find the number of unpaired electrons in [Mn(H2O)6]2+ .
(At. no. of Mn = 25)

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answer is 5.

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Detailed Solution

Since H2O is a weak ligand, it will not cause pairing of electrons in the metal ion Mn2+. Thus electronic configuration of the metal (Mn2+) in the complex
will be

Mn 25 2+:1s22s22p63s23p63d5

i.e. 5 unpaired electrons.

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