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Q.

Consider

Reaction-I; Gabriel phthalimide synthesis

Reaction-II; Hoffman's hypobromite reaction.

Correct statement about these reactions is

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a

Both I and II are useful to prepare 10 aryl amine

b

I is useful to prepare 10 aryl amine but II cannot be used to prepare 10 aryl amine

c

II is useful to prepare 10 aryl amine but I cannot used to prepare 10 aryl amine

d

Both I and II are not useful to prepare 10 aryl amine

answer is C.

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Detailed Solution

I) The nucleophile formed is

Question Image

It cannot react with C6H5-X to form C6H5-X;

 C6H5-X in non reactive towards nucleophilic substitution reactions due to resonance;

Primary aryl amines cannot be prepared;

 II)Z-CONH2+Br2+4NaOHZNH2+Na2CO3+2NaBr+H2O;Z can  be   RorC6H5;Any primary amine can be prepared; 

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