Conversion of $C H_{4}$ to $C H_{3} C l$ is an example of which of the following reaction

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Electrophilic substitution

Free radical addition

Nucleophilic substitution

Free radical substitution

answer is D.

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Detailed Solution

Substitution reactions that are brought about by free radical are called free-radical substitution reactions.

$\begin{aligned} {CH}_{4} + {Cl}_{2} \underset{or light}{\overset{heat}{⟶}} \\ {CH}_{3} + {CH}_{2} {Cl}_{2} + {CHCl}_{3} + {CCl}_{4} + HCl \end{aligned}$

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