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Q.

Copper is the most noble of first row transition metals and occurs in small deposits in several countries. Ores of copper include chalcanthite CuSO45H2O atacanite Cu2Cl(OH)3 cuprite Cu2O copper glance Cu2S, and malachite Cu2(OH)2CO3. However, 80% of the world copper production comes from the ore chalcopyrite CuFeS2. The extraction of copper from chalcopyrite involves partial roasing, removal of iron and self-reduction.

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a

Cu2S and FeO

b

Cu2O and FeO

c

Cu2O and Fe2O3

d

CuS and Fe2O3

e

FeO

f

FeS

g

Fe2O3

h

FeSiO3

i

S

j

O2−

k

S2−

l

SO2

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Detailed Solution

During partial roasting, CuFeS2 is first converted to Cu2S and FeS. Further, as iron is more reactive than copper, FeS. is preferentially oxidised to FeO. This partial roasting of chalcopyrite produces Cu2S and FeO.

CuFeS2+O2ΔCu2S+2FeS+SO22FeS+O2ΔCu2S+2FeS+SO2

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