Q.

Copper(II) hydroxide,  Cu(OH)2, has Ksp=2.2×1020 For the reaction below, Keq=4.0×107 What is Kf for CuNH342+?

Cu(OH)2(s)+4NH3(aq)CuNH342+(aq)+2OH(aq)

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a

8.8×1027

b

5.5×1014

c

1.8×1013

d

1.1×1026

answer is C.

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Detailed Solution

Cu(OH)2(s)Cu2++2OH; KspCu2++4NH3Cu(NH3)42+; KfCu(OH)2+4NH3CuNH342++2OHKeq=Ksp×Kf

Kf=4×1072.2×1020=1.8×1013

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