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Q.

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Correct decreasing order of acidic strength of the above organic compounds is

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a

B > C > A > D

b

C > D > B > A

c

D > B > A > C

d

B > A > C > D

answer is C.

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Detailed Solution

-NO2 …. -I, -M…… EWG at para position.
-CH3 …. +I, +R……EDG  at para position.
-OCH3 …. -I, +M ….EDG at para position.
Electron donating power :  -OCH3 > -CH3
EWG increase acidic strength.
EDG decrease acidic strength.
Acidic strength :
B > A > C > D

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