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Q.

Correct decreasing order of reducing power in 15th group hydrides is

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a

BiH3>NH3>SbH3>AsH3>PH3

b

NH3<PH3<AsH3<SbH3<BiH3

c

BiH3<SbH3<AsH3<PH3<NH3

d

BiH3>SbH3>AsH3>PH3>NH3

answer is D.

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Detailed Solution

All the hydrides of 15th  , 16th & 17thgroup are covalent

In 15th  , 16th & 17thgroup hydrides Down the group ,As the size of the atom increases ,

Affinity with Hydrogen decreases. Due to which (X=the central atom)

A) X-H bond enthalpy decreases

B)Thermal stability decreases

C) X-H bond length increases

D) Acidic strength increases

E) Reducing power increases

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