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Q.

Correct increasing order for the wavelength of absorption in the visible regin for the complexes +3 is

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a

CoH2O63+,CoNH363+,Co(en)33+

b

CoNH363+,Co(en)33+,CoH2O63+

c

Co(en)33+,CoNH363+,CoH2O63+

d

CoH2O63+,Co(en)33+,CoNH363+

answer is B.

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Detailed Solution

The increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+ is [Co(en)3​]3+<[Co(NH3​)6​]3+<[Co(H2​O)6​]3+

The decreasing order of ligands strength is en > NH3​ >H2​O. Stronger ligand causes greater splitting between two energy levels. 

The energy of light absorbed is more and the wavelength of light absorbed is less for the stronger ligand.

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