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Q.

Correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+is

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a

[Co(H2O)6]3+,[Co(NH3)6]3+,[Co(en)3]3+

b

[Co(en)3]3+,[Co(NH3)6]3+,[Co(H2O)6]3+

c

[Co(H2O)6]3+,[Co(en)3]3+,[Co(NH3)6]3+

d

[Co(NH3)6]3+,[Co(en)3]3+,[Co(H2O)6]3+

answer is C.

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Detailed Solution

detailed_solution_thumbnail

The order of the ligand in the spectrochemical series H2O<NH3<en
Thus, the wavelength absorbed will be in the opposite order i.e., 
[Co(H2O)6]3+>[Co(NH3)6]3+>[Co(en)3]3+

wave length of light absorbed 1strength of ligand

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