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Q.

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Correct increasing order of stability of the given carbocations is

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a

B, D, A, C

b

B, A, C, D

c

C, A, D, B

d

C, D, A, B

answer is C.

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Detailed Solution

–CH3 at para position ..... EDG
–NO2 at para position ..... EWG
–Cl at para position ..... EWG
Electron withdrawing power of –NO2 > –Cl
EDG disperses the positive charge and stabilizes the carbocation
EDG intensifies the positive charge and destabilizes the carbocation
Stability of C < D < A < B

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