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Q.

Correct order of acidity is represented in ?

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a

CHCH>CH3CCH>CH2=CH2>CH3CH3 

b

CHCH>CH2=CH2>CH3CCH>CH3CH3 

c

CH3CH3>CH2=CH2>CH3CCH>CHCH

d

CH2=CH2>CH3CH=CH2>CH3CCH>CHCH 

answer is A.

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Detailed Solution

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Alkanes, alkenes and alkynes follow the following trend in their acidic behavior :

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sp-hybridised carbon is more electronegative than sp2 -hybridised carbon which is further more electronegative than sp3 -hybridised carbon.

In ethyne, proton can be released more easily than ethene and ethane.

Among alkynes the order of acidity is:

HCCH>CH3CCH>>CH3CCCH3

This is explained on the basis of +I effect of alkyl group.

Therefore, the correct order is represented in option 1.

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