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Q.

Correct order of basic strength of given amines is

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a

Me3N>Me2NH>Me−NH2>NH3( gas phase )

b

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c

Me2N>Me3N>MeMH2 (protic solvent) 

d

Et2NH>EtNH2>Et3NH2 (protic solvent) 

answer is A.

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Detailed Solution

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In gaseous phase the tertiary amine takes a pyramidal structure and the lone pair is available for donation to the proton. But in liquid state stearic course comes into consideration.

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