Q.

Correct order of bond length is:

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a

CH3F<CH2F2:CH bond angle

b

P4O6>P4O10:POP bridging bond length

c

B2F4>B2H4:BB bond length

d

All of the above

answer is C.

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Detailed Solution

Given the nature of the P-O bonds in both molecules, it can be deduced that P4O10 is P-O bond length is shorter than P4O6 is due to the existence of double bonds.
As a result, the P-O bond in P4O10 is weaker than that in P4O6.
P-O-P bond has greater % p-character in P4O6 as l.p. on P has greater %s-character
Thus, the option C is correct.

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