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Q.

Correct order of priorities of various groups according to CIP rules is

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a

–OH > – NH2 > – COOH > – CHO

b

– COOH > – CHO > – OH > – NH2

c

–Br > – OH > – CN > –COOH

d

–NH2 > – NO2 > – CH3 > – C2H5

answer is A.

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Detailed Solution

According to CIP rules, the group in which the directly attached atom has highest atomic number is given the highest priority ;
If the directly attached atom is the same then the next atom must be considered ;
Each double bonded (or) triple bonded atom is considered as two such (or) three such atoms respectively.
   OH >  NH2 >  COOH > CHO   OH >  NH2 > C, O, O, O > C, O, O, H
 

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