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Q.

Correct order of spin only magnetic moment of the following complex ions is:

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a

[Co(C2O4)3]3>[CoF6]3>[FeF6]3

b

[FeF6]3>[Co(C2O4)3]3>[CoF6]3

c

[FeF6]3>[CoF6]3>[Co(C2O4)3]3

d

[CoF6]3>[FeF6]3>[Co(C2O4)3]3

answer is A.

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Detailed Solution

[FeF6]3:Fe3+:3d5,F1   is a weak field ligand.
 Question Image
Number of unpaired electrons = 5  μ=35BM
  [CoF6]3:Co3+:3d6
 Question Image
Number of unpaired electrons = 4  μ=24BM
[Co(C2O4)3]3:CO3+:3d6   Oxalate is a strong field ligand
 Question Image
Number of unpaired electrons = 0  μ=0BM

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