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Q.

Correct statement about PCl5 ,IF7 and SF6 is

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a

All I-F bond lengths in IF7 are identical

b

All S-F bond length in SF6 are identical

c

5In SF6 two S-F bonds are shorter than rest four S-F bonds

d

All P -Cl bond lengths in PCl5 are identical

answer is A.

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Detailed Solution

Question Image
Question Image

PCl5

bp=5
Total =5
Sp3d
Trigonal bipyramidal

SF6​ [see image]
bp=6
Ip=0
Total =6
Sp3d2
Octahedral

IF7​ [see image]
bp=7
Ip=0
Total =7
Sp3d3
pentagonal bipyramidal 

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