Correct statement about PCl₅ ,IF₇ and SF₆ is

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All I-F bond lengths in IF₇ are identical

All S-F bond length in SF₆ are identical

₅In SF₆ two S-F bonds are shorter than rest four S-F bonds

All P -Cl bond lengths in PCl₅ are identical

answer is A.

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Detailed Solution

PCl₅

bp=5
Total =5
Sp3d
Trigonal bipyramidal

SF₆ [see image]
bp=6
Ip=0
Total =6
Sp3d2
Octahedral

IF7 [see image]
bp=7
Ip=0
Total =7
Sp3d3
pentagonal bipyramidal

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