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Q.

Correct statement among the following is

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a

In aqueous solution, acidic strength of HClO4 > HCl

b

Blood is a basic buffer

c

NaCl can be precipitated from its saturated solution by passing HCl gas.

d

In the aqueous solution of FeCl3, Cl ion undergoes hydrolysis

answer is C.

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Detailed Solution

(1) In the aqueous solution, both HClO4 and HCl completely ionize.
     acidic strength of HClO4=HCl
(2) Blood is an acidic buffer H2CO3/HCO3
     Its pH=7.4
(3) Addition of HCl to NaCl solution increases the ionic product of NaCl. Ionic product exceeds solubility product.NaCl gets precipitated.
(4) Fe+3+3Cl+3H2OFe(OH)3+3H++3Cl
                              or    
    Fe+3+3H2OFe(OH)3+3H+

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