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Q.

Correct statement(s) among the following is/are

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a

The atomic orbitals in the valence shell of an atom with unpaired electrons only participate in hybridization.

b

πbond is formed by sidewise overlapping of two orbitals which have their axes  parallel to each other.

c

The sigma (σ) bond strength of different orbitals overlapping will be in the order   2S2 S  >  2S2P   >  2P2P

d

BF3 is more covalent than  BeF2

answer is A, C.

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Detailed Solution

The strength of sigma bonds formed by the axial overlap of s- or p-orbitals of 2nd shell of participating atoms decreases as:
p-p>p-s>s-s

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Correct statement(s) among the following is/are