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Q.

Correct statements among the following are :

A) At 298 K, pH of an acidic buffer is always less than seven.

B) Buffer capacity of acidic buffer is maximum when its PH=PKa(of weak acid present in it).

C) Equimolar mixture of NH4OH and HCl can act like a basic buffer.

D) A mixture of NH4Cl (excess) and NaOH acts as buffer.

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a

A and D only

b

B and C only

c

A, B, C and D

d

B and D only

answer is C.

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Detailed Solution

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A) At 298 K, PH of an acidic buffer can be greater or lesser than or equal to 7

B) Buffer capacity of acidic buffer is maximum when its pH is equal to pKa

C) Equimolar mixture of NH4OH and HCl cannot act like a basic buffer

     Mixture of excess weak base and limited strong acid can act like buffer

D) NH4+ (excess) + NaOH acts as a buffer.

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