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Correct statements among the following are
a) PCl₃ is obtained when white phosphorus is heated with thionyl chloride
b) When white phosphorus is a heated with sulphurous chloride PCl₃ is obtained
c) PCl₃ is a colourless only liquid while PCl₅ is an yellowish white powder
d) PCl₃ converts Ag to AgCl on heating

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a c d only

a b d only

a b c only

a and c only

answer is C.

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Detailed Solution

PCl₃ obtained by the action of thionyl chloride with white phosphorus.

$P_{4} + 8 {SOCl}_{2} \to 4 {PCl}_{3} + 4 {SO}_{2} + 2 S_{2} {Cl}_{2}$

PCl₅ is a yellowish white powder and in moist air. PCl₃ is a colourless oily liquid.

$2 Ag + {PCl}_{5} \to 2 AgCl + {PCl}_{3}$

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