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Q.

Correct statements among the following is/are
a) NO2 is a reddish brown paramagnetic gas but its dimer N2O4 is colorless diamagnetic solid.
b) NO2 is mixed anhydride
c) N2O3 is mixed oxide
d) HNO2 exists in two tautomeric forms

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a

only a and d are correct

b

all are correct

c

only a, b and d are correct

d

only a, b, c are correct

answer is B.

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Detailed Solution

NO2 is a brown color gas but its dimer which is N2O4 is a colorless solid.

Nitrogen dioxide a mixture of anhydride means the compound forms a mixture of two acidic anhydrides when reacts with water.

Dinitrogen trioxide is prepared by mixing equal parts of nitric oxide and nitrogen dioxide.

Nitrous acid exists in two tautomeric forms
(1) nitro form as in nitro alkanes
(2) nitrite form as in alkyl nitrite

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