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Q.

Correct statements are
A) All Lanthanoids are more reactive than Calcium
B) Ce+4 is a powerful oxidizing agent and its kinetics is rapid
C) LuOH3is a stronger base than  LaOH3
D) Samerium is steel hard
E) IP1of early actioniods is lesser than that of early Lanthanoids
 

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a

All of these

b

D only 

c

D,E only

d

B, D, E only

answer is C.

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Detailed Solution

Initial Lanthanoids resemble ‘Ca’ and latter members resemble ‘Al’ in their reactivity;

 Ce+4 is a powerful oxidizing agent in Analytical chemistry because ECe+4/Ce+30  has high positive value (1.77V) but its action is slow;
La(OH)3to Lu(OH)3 basic strength decreases due to decrease in ionic size and ionic character;

 

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