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Correct statements regarding VSEPR theory are
A) Electron pairs tend to occupy such positions in space around central atom to minimise the repulsions
B) A multiple bond is treated as if it is a single electron pair
C) Applicable to any one of the resonance structure representing a molecule
D) Bond pair – bond pair repulsions can never be stronger than lone–lone pair repulsions

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A,C,D only

B,C,D only

C,D only

A,B,C only

answer is D.

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Detailed Solution

In the case of dimethyl ether and chlorine monoxide

And

bp – bp repulsions exceed lp–lp repulsions. This is due to bulky alkyl groups in ether and back bonding in chlorine monoxide

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