[Cr(H₂O)₆]Cl₃ and [Cr(H₂O)₄Cl₂]Cl.H₂O are hydrate isomers. Their colours are respectively

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blue and green

red and blue

yellow and green

violet and green

answer is A.

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Detailed Solution

The given isomer are solvate isomers which differ by the number of solvent molecules that are directly bonded to the metal ion. The color of these isomers changes accordingly with the type of ligands attached to the central metal ion.

Color of [Cr(H₂O)₆]Cl₃ is violet whereas color of [Cr(H₂O)₄Cl₂]Cl.H₂O is green.

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