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Q.

Cr2O72orangePH=xCrO42(yellow) . Equilibrium is attained at a pH=x then the incorrect statement regarding the process is

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a

pH < x,  orange colour dominates

b

pH = x, colour of the reaction mixture is intermediate of orange and yellow

c

pH >x, yellow colour dominates

d

pH has no influence on equilibrium state

answer is D.

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Detailed Solution

pH = x, dynamic equilibrium exists

In acidic medium,CrO42  changes to Cr2O72

In basic medium, Cr2O72 changes to CrO42

 pH>x...........basic medium – yellow CrO42  but not orange Cr2O72                                                              

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