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Q.

${CrCl}_{3} \underset{{NH}_{4} OH}{\overset{{NH}_{4} Cl}{\to}} (A) \overset{{Na}_{2} O_{2} soln}{\to} (B) \overset{Lead aceted}{\to} (C) Yellow ppt .$
Which $d$ -orbital is not taking part in hybridisation of species $B$ ?

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a

$d_{x y}$

b

$d_{y z}$

c

$d_{z x}$

d

$d_{x^{2} - y^{2}}$

answer is D.

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Detailed Solution

$^{'} B^{'}$ is ${CrO}_{4}^{2 -}$ ( $d^{3} s$ hybridization)

$d_{x^{2} - y^{2}}$ does not participate in hybridization

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