Q.

[Cr(H2O)6]Cl3 has a magnetic moment of 3.83 B.M. The correct distribution of 3delectrons in the chromium of the complex is

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a

3dxy1,3dyz1,3dz2

b

3d1xy,3d1yz,3d1zx

c

3dxy1,3d1x2y2,3d1y2

d

3dx2y21,3d1z2,3d1xz

answer is B.

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Detailed Solution

3.83=nn+2so,n=3

So, these are three unpaired e-s. Based on crystal field splitting the orbital of t2g set have one e- each.

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