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Q.

[Cr(H2O)6]Cl3 and [Cr(H2O)4Cl2]Cl.H2O are hydrate isomers. Their colors are respectively

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a

violet and green

b

yellow and green
 

c

 red and blue

d

blue and green

answer is A.

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Detailed Solution

It is given to find out the colors of [Cr(H2O)6]Cl3 and [Cr(H2O)4Cl2]Cl.H2O

Hydrate isomerism is a kind of ionization isomerism. 
In this, compounds have different no. of solvent molecules bonded to the metal ion.

Explanation

Different numbers of water molecules are present in the coordination sphere and the ionization sphere of the chemicals in question.
As a result, they show hydrate isomerism.

Hence the correct answer is A)violet and green

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[Cr(H2O)6]Cl3 and [Cr(H2O)4Cl2]Cl.H2O are hydrate isomers. Their colors are respectively