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Q.

Critical constants for a real gas are given as

TC=180KVC=0.1231L/molePC=45atm

The correct statement for the real gas is :

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a

The actual volume of single gas molecule is 0.123×1036.023×1023cc

b

b=3×0.123Lmol1

c

Gas cannot be liquefied at 200 K

d

The Boyle's temperature is less than 1.80 K

answer is D.

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Detailed Solution

(a) VC=3b volume of 1 molecule =43πr3

(b) b=0.12313=VC12NA

(c) TB=278×180K

(d)  At T>TC gas can't be liquefied.

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