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Q.

Critical temperature for a particular gas is - 177° C then for which of the following case value of compressibility factor of the gas may be more than unity?

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a

 At 60°C and 10 atm

b

At 0°C and 2000 atm

c

At 0°C and 0.01 atm

d

At 60°C and 0.01 atm

answer is B, C, D.

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Detailed Solution

Critical temperature In kelvin,

TC=96K

Thus, the Boyle's temperature,

⇒TB=278×96=324 K or 51∘C

All the cases are correct here except, at 0°C and 0.01 atm.

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