Q.

Cu2++2e-Cu;logCu2+ vs E graph is of the type as shown in figure where OA = 0.34 V, then electrode potential of the half-cell of CuCu2+(0.1M) will be

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a

0.34+0.05912V

b

0.34 V

c

none of these

d

0.34 + 0.0591V

answer is A.

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Detailed Solution

ECu/Cu2+=0.34+0.0592

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Cu2++2e-→Cu;log⁡Cu2+ vs E graph is of the type as shown in figure where OA = 0.34 V, then electrode potential of the half-cell of Cu∣Cu2+(0.1M) will be