Q.

CuSO4·5H2O is blue in colour where as anhydrous CuSO4 is colourless why?

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Detailed Solution

In CuSO4 .5H2O water acts as ligand as a result it causes crystal field spliting. Hence d-d transiton is possible thus CuSO4 .5H2O is coloured. In the anhydrous CuSO4 due to the absence of water, crystal field spliting is not possible hence it is colourless.

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