Q.

CuSO4+NH4OH                       excess Deep blue solublecomplex salt

The correct statement regarding the complex is/are:

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a

It gives black precipitate of CuS when treated with H2S.

b

All of these

c

It has square planar geometry.

answer is D.

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Detailed Solution

Since CuNH34SO4 has one unpaired electron, square planar anddsp2 hybridization.

CuNH34SO4H2SCuS (Black) 

Hence all the given options are correct.

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