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Q.

Decomposition of ozone follows the given mechanism. From the mechanism select the option which is not correct

step 1: O3(g)K1K2O2(g)+O(g)         [fast]

step 2: O3(g)+O(g)K32O2(g)      [slow]

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a

Rate of formation of ozone will decrease with increase in concentration of oxygen gas

b

Overall rate will be dependent on rate of (ii) step.

c

Molecularity of step (ii) will be 2.

d

Order of the reaction is equal to 2.

answer is B.

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Detailed Solution

slow step is rate determining step.

Hence rate of reaction is given as:

 rate =k2[O]O3

by chemical eqn

k1=03[0]O3[O]=k1O3O2

r=K3×K1K2×O32O21

So, rate =k1k2O32O21

r=kO32O21

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