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Q.

Define ebullioscopic constant?

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Detailed Solution

The ebullioscopic constant is a solvent’s fixed value that tells how much its boiling point rises when one mole of solute is dissolved per kilogram of that solvent. 

It is the proportionality constant Kb in the boiling point elevation formula. The ebullioscopic constant, written as Kb, measures the sensitivity of a pure solvent’s boiling point to the presence of a non-volatile solute. If you add a solute, the boiling point goes up. The rise in temperature is directly proportional to the molality of the solution.

Key formula: ΔTb = Kb × m × i, where:

  • ΔTb = elevation in boiling point.
  • Kb = ebullioscopic constant of the solvent.
  • m = molality of the solute (moles per kg of solvent).
  • i = van ’t Hoff factor (accounts for ionization or association).
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